Upgradation of sugarcane bagasse lignin: Fractionation to cyclic alcohols production
نویسندگان
چکیده
Reductive catalytic fractionation (RCF) is a new class of process that produces mono phenolics close-to-theoretical maximum yield by preserving the biomass polysaccharides as solid residues under hydrogen atmosphere or transfer conditions. Herein, hydrous ruthenium oxide deposited on carbon (HRO@C) and HY-zeolite (HRO@HYZ) catalysts are prepared characterized different analytical techniques (TGA, TPD, TPR, XRD, TEM, XPS, physisorption chemisorption). Both have been used for RCF sugarcane bagasse (SCB). Effects catalyst acidity, reaction time, pressure, temperature, solvent SCB investigated. Solid after FT-IR, TGA, fibertec to identify effects conditions lignin-first delignification efficiency (LFDE). High acidity HRO@HYZ favors high degree LFDE (81.2 %) than HRO@C (55.8 %). However, alkyl-substituted phenolic monomers (ASPMs) selectivity 69 % 55.7 HRO@HYZ, respectively, same NMR GC-FID/GC-MS analysis indicate presence ASPMs in resulted lignin bio-oil. Moreover, fractionated bio-oil upgradation upgraded product confirms > 95 conversion bio-oil, which over 90 towards alkylated cyclic alcohols. • Catalysts with acidities were investigated SCB. favours delignification. Alkyl-substituted differed from Severe promoted hemicellulose cellulose depolymerization. Fractionated successfully converted (>95 alcohols (>90
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ژورنال
عنوان ژورنال: Catalysis Today
سال: 2023
ISSN: ['0920-5861', '1873-4308']
DOI: https://doi.org/10.1016/j.cattod.2022.05.037